I suppose it could be done, but I suspect the economics of it are a big reason it's not done. I found a resource addressing the exact question of EN-plating a firetube boiler which indicated that electroplating "in-situ", especially for such a mechanically intricate piece as a boiler, would be prohibitively costly due to the complexity of bringing the process to the workpiece, and ensuring thorough coverage. Galvanic corrosion may also be a factor, or it may place additional restrictions on the water supply.